Dichloroborane-dimethyl sulfide, a highly selective reducing agent for reduction of organyl azides to amines. Stephan König, Ivar Ugi, Hans J. Schramm. The To the solution of azides (0.03 mol) and ammonium chloride (0.07 mol) in ethyl alcohol (80 mL) and water (27 3 A stereocontrolled synthesis of 1-amino-2,5-anhydro-3,4,6-tri-O-benzyl-1-deoxy-d-glucitol. in high yields (Entries 2 and 4). hydrogen, a general method for the as hydrogen donor, resulted in more than 65% yield (Table 1, Entry Alkyl azides and acyl azides were reduced to the corresponding amines and amides with zinc and ammonium chloride as reducing agent under mild conditions in good to excellent yield. The reductions F. Effenberger, Andreas Kremser, Uwe Stelzer. of primary amino group in organic synthesis because of the easy preparation A CHEMOSELECTIVE CONVERSION OF ALKYL AND ARYL AZIDES TO AMINES WITH SODIUM HYDROGENTELLURIDE. Diganta Pathak, Dhrubojyoti D Laskar, Dipak Prajapati, Jagir S Sandhu. Mohammad Ali Karimi Zarchi, Rahman Nabaei, Saeed Barani. Highly Stereoselective Total Synthesis of Multiply Protected 3-Amino-3,6-dideoxyaldohexoses (Mycosamine/Mycaminose) by Aldol Condensation Reaction, Mediated by Tin Triflate, of Tricarbonyliron/α-Aminodienone Complexes. 3). The latter reaction path dominates when primary amines are present in the sample. Chinese Journal of Chemistry 2006 , 24 (6) , … Watthey J.W.H., Stanton J.L., Desai M., Babiarz J.E., Finn B.M.. Ksander G.M., Erion M., Ruan A.M., Diefenbacher C.G., El-chehabi L., Cote D., Levens N.. Parsons W.H., Davidson J.L., Taub D., Aster S.D., Thorsett E.T., Patchett A.A.. Boyer S.K., Pfund R.A., Portmann R.E., Sedelmeier G.H., Wetter H.F.. Schoen W.R., Pisano J.M., Prendergast K., Wyvratt Jr. M.J., Fisher M.H., Cheng K., Chan W.W.-S., Butler B., Smith R.G., Ball R.G.. Attwood M.R., Hassall C.H., Kröhn A., Lawton G., Redshaw S.. Bosch I., Costa A.M., Martín M., Urpí F., Vllarrasa J.. Mungall W.S., Greene G.L., Heavner G.A., Letsinger R.L.. Bartra B., Romea P., Urpí F., Vilarrasa J.. Boruah A., Baruah M., Prajapati D., Sandhu J.S.. Cho S.-D., Choi W.-Y., Lee S.-G., Yoon Y.-J., Shin S.C.. Hollywood F., Nay B., Scriven E.F.V., Suschitzky H., Khan Z.U.. Suzuki T., Tanaka S., Yamada I., Koashi Y., Yamada K., Chida N.. co-solvents of ethyl acetate and water, ethyl alcohol and water as well as Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH. Grafting of buckminsterfullerene onto polythiophene: novel intramolecular donor-acceptor polymers. Facile Syntheses of C2-Symmetrical HIV-1 Protease Inhibitors. It is widely known that most of primary amines are biologically active compounds https://doi.org/10.1021/acschembio.6b00398, https://doi.org/10.1021/bk-1996-0641.ch010, https://doi.org/10.1007/s13738-020-01909-y, https://doi.org/10.1016/j.bmcl.2015.07.100, https://doi.org/10.1002/9783527688166.ch8, https://doi.org/10.1016/j.tetlet.2013.08.083, https://doi.org/10.1007/s11426-010-3199-5, https://doi.org/10.1016/j.tetlet.2009.06.059, https://doi.org/10.1080/00397910701739097, https://doi.org/10.1016/j.bmc.2007.02.036, https://doi.org/10.1002/9780470125946.ch7, https://doi.org/10.1080/10426500490466544, https://doi.org/10.1016/S0960-894X(03)00098-2, https://doi.org/10.1016/S0040-4020(02)01322-4, https://doi.org/10.1016/S0008-6215(02)00132-5, https://doi.org/10.1002/1099-0690(200011)2000:22<3693::AID-EJOC3693>3.0.CO;2-S, https://doi.org/10.1002/1097-4628(20001003)78:1<109::AID-APP140>3.0.CO;2-6, https://doi.org/10.1016/S0040-4039(00)01373-3, https://doi.org/10.1080/00397919808005968, https://doi.org/10.1080/00397919808003077, https://doi.org/10.1016/S0925-3467(97)00063-3, https://doi.org/10.1016/S0957-4166(97)00141-9, https://doi.org/10.1016/0040-4039(96)00844-1, https://doi.org/10.1016/0040-4020(96)00078-6, https://doi.org/10.1016/0957-4166(96)00044-4, https://doi.org/10.1016/0040-4039(95)01721-S, https://doi.org/10.1016/0040-4039(95)00341-9, https://doi.org/10.1016/0022-328X(94)24776-F, https://doi.org/10.1080/00397919408011505, https://doi.org/10.1080/00397919308011148, https://doi.org/10.1016/S0022-1139(00)81256-7, https://doi.org/10.1080/10426509108038833, https://doi.org/10.1016/B978-0-08-052349-1.00153-0, https://doi.org/10.1016/S0008-6215(00)90874-7, https://doi.org/10.1016/S0003-2670(00)84511-0, https://doi.org/10.1016/S0010-8545(00)82079-2, https://doi.org/10.1016/S0022-328X(00)92817-1.